Welcome to the Plietker Research Group
Entwicklung neuer übergangsmetallkatalysierter Reaktionen zum gezielten Aufbau von neuen C-C-, C-N-, C-S- und C-O-Bindungen, asymmetrische Synthese, Entwicklung einer parallelen, automatisierbaren, modularen Kohlenhydratsynthese zum Aufbau strukturell definierter Substanzbibliotheken, Naturstoffsynthese.
Development of transition metal catalyzed reaction for the selective generation of new C-C-, C-N-, C-S- and C-O-bonds; asymmetric synthesis; development of a parallel, automatable, modular carbohydrate synthesis for the generation of a structural defined substance library; natural product synthesis.
Plietker-Group moved to Dresden!!! | 18:14, Jul 12 2020 |
Finally we can announce that our moving to Technische Universität Dresden was succesfully. Officially we are at TU since April 1, 2020 but because of the Corona-Pandemia the moving was delayed according to the restrictions. Our group is replacing the Metz group in the Department of Organic Chemistry (Chair of Organic Chemistry I) and we're looking forward to our time in this new scientific surrounding. |
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Fabi's and Franzi's paper was published in Catalysis Science & Technology | 12:23, Jul 27 2020 |
Their publication describes the efficient stereoselective hydroboration of internal alkynes using the Fe-H complex FeH(CO)(NO)(PPh3)2 and either pinacolborane or bis(pinacolato)diboron. The boron source is essential for a mechanistic dichotomy and therefore for the regioselectivity. Good work, Fabi and Franzi! Congratulations! DOI |
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Asli's paper was accepted for publication in European Journal of Organic Chemistry! | 11:30, Jan 07 2020 |
A catalytic method for the direct intramolecular amination of aryl vinyl azides to give the corresponding indole derivatives is described. The nucleophilic Fe‐complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) is used as catalyst and the procedure leads to good to excellent yields. Good work, Asli! Congratulations! DOI |
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Marie's paper was published in Organic Letters! | 11:30, Jan 07 2020 |
The catalytic cyclopropanation of enynes to substituted propargyl cyclopropanes under thermal/photochemical conditions is described. In this method diazoesters are used as carbene surrogates and the nucleophilic Fe-complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) as catalyst. Good work, Marie! Congratulations! DOI |
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Pascal's and Franzi's paper was published in Chemistry-A European Journal! | 11:01, Jan 07 2020 |
The catalytic and selective deuteration of polyfunctional organic molecules using [RuCl2(PPh3)3] and D2O is described. By changing the additive and the amount of zink powder, orthogonal chemoselectivities are observed. Good work, Pascal and Franzi! Congratulations! DOI |
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Jianan Li has joined for his Ph.D. | 15:16, Oct 28 2019 |
Jianan got the Chinese Government Scholarship by the CSC (Chinese Scholarship Council). Congratulations! He will focus on iron complex synthesis and iron-catalysis. We wish you a lot of fun and success! |
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Arnar Gudmundsson has joined the group as an exchange Ph.D. student | 15:18, Oct 28 2019 |
Arnar is doing his Ph.D. in the Bäckvall group and will work in our group for three month. During this time he will focus on the modification of iron-complexes and their application in cycloisomerizations. |
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Asli's paper was accepted for publication in Chemistry - An Asian Journal! | 15:21, Nov 06 2019 |
The successful use of the nucleophilic iron complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) as a proton‐transfer catalyst in the cyclocondensation reaction between azides and ketones is reported. The reason for the formation of 1,2,3-triazoles instead of the C−H amination product seems to be a significantly faster proton‐transfer catalysis than the nitrene‐transfer catalysis. An example of a successful sequential Dimroth triazole–indoline synthesis to the corresponding triazole‐substituted indolines is presented. Good work, Asli! Congratulations! DOI |
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Annika's review was accepted for publication in Catalysis Science & Technologie! | 15:22, Nov 06 2019 |
Intramolecular aminations of C–H bonds represent an elegant synthetic way to form important N-heterocycles. Organometallic complexes allow to catalyze the C–H amination under mild conditions. In this review, the most important developments to this field of research concerning Fe-catalysts are summarised and categorized by open-shell (radical) and closed-shell (non-radical) mechanisms. Congratulations! DOI Read More |
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Lei completed his Ph.D. | 09:00, Jun 03 2019 |
Lei has successfully defended his Ph.D. thesis. Congratulations and all the best for your future! |
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